NMR and QNS investigation of molecular liquids

NMR relaxation results are summarized for 18-crown-6 ether, for water (H172O and D2O) in dimethylsulfoxide, for tetrahydrofuran and for methyl iodide in the corresponding clathrate hydrates. Rotational diffusion coefficients are derived for the crown ether. Deuteron quadrupole-coupling constants are...

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Bibliographic Details
Published in:Electrochimica acta 1988-09, Vol.33 (9), p.1195-1202
Main Author: Zeidler, M.D.
Format: Article
Language:English
Subjects:
Catalysis
Catalysts: preparations and properties
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
General. Nomenclature, chemical documentation, computer chemistry
Theory of reactions, general kinetics
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:NMR relaxation results are summarized for 18-crown-6 ether, for water (H172O and D2O) in dimethylsulfoxide, for tetrahydrofuran and for methyl iodide in the corresponding clathrate hydrates. Rotational diffusion coefficients are derived for the crown ether. Deuteron quadrupole-coupling constants are obtained for D2O in mixture with dimethylsulfoxide. High-pressure self-diffusion constants obtained by the NMR spin-echo method are presented for ethanol and 1-propanol. A QNS investigation of 18-crown-6 ether is conducted in order to supplement the NMR data.
ISSN:0013-4686
1873-3859
DOI:10.1016/0013-4686(88)80149-X