Electrochemical behaviour of 1-methyl-2,4-dicyanopyridinium ion in dipolar aprotic solvents

The electrochemical reduction of 1-methyl-2,4-dicyanopyridinium cation to a relatively stable, reversible, radical (or anion) in aprotic solvent is described. The subsequent chemical reactions of the electro generated anion have been investigated.

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Bibliographic Details
Published in:Electrochimica acta 1990, Vol.35 (7), p.1185-1188
Main Author: Carelli, I.
Format: Article
Language:English
Subjects:
Adsorption
Chemistry
dihydropyridine carbanions
dihydropyridine radicals
electrochemical reduction
Electrochemistry
Exact sciences and technology
General and physical chemistry
Study of interfaces
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Description
Summary:The electrochemical reduction of 1-methyl-2,4-dicyanopyridinium cation to a relatively stable, reversible, radical (or anion) in aprotic solvent is described. The subsequent chemical reactions of the electro generated anion have been investigated.
ISSN:0013-4686
1873-3859
DOI:10.1016/0013-4686(90)80037-O