Synthesis of zirconium polyesters

Zirconium polyesters were prepared from the polycondensation of Cp 2ZrCl 2 with various diacid salts utilizing the solution and interfacial methods. The polymers contain the following repeating structure: ▪ The reactive species in the solution systems is believed to be the Cp 2Zr 2+ cations. On a pr...

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Bibliographic Details
Published in:European polymer journal 1972-01, Vol.8 (2), p.215-220
Main Author: Carraher, C.E.
Format: Article
Language:English
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Summary:Zirconium polyesters were prepared from the polycondensation of Cp 2ZrCl 2 with various diacid salts utilizing the solution and interfacial methods. The polymers contain the following repeating structure: ▪ The reactive species in the solution systems is believed to be the Cp 2Zr 2+ cations. On a préparé des polyesters de zirconium par polycondensation du Cp 2ZrCl 2 avec divers sels de diacides en utilisant des méthodes en solution et interfaciales. Les polymères contiennent le motif suivant: ▪ On pense que l'espèce réactive lors de la réaction en solution est le cation Cp 2Zr 2+. Mediante policondensazione di Cp 2ZrCl 2 con vari sali biacidi, impiegando metodi di soluzione e interfaccia, si sono preparati dei poliesteri di zirconio. Tali polimeri contengono il seguente gruppo ripetitivo: ▪ Si crede che le specie reattive in soluzione siano i cationi Cp 2Zr 2+. Zirkonium Polyester wurden durch Auflosung und Grenzflachen Polykindensation aus Cp 2ZrCl 2 mit verschieden Disanersalz hergestellt. Die Polymeren halen die folgende Struktur: ▪
ISSN:0014-3057
1873-1945
DOI:10.1016/0014-3057(72)90028-6