Mechanochemically initiated polymerizations—5. Polymerization by vibratory milling of acrylamide and methacrylamide

Mechanochemical polymerization by vibratory milling of acrylamide and methacrylamide is discussed. The influences of duration, nature of medium and temperature are examined. The polymers are characterized by elemental analysis, i.r.-spectroscopy. X-ray and by determination of some properties. An ani...

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Bibliographic Details
Published in:European polymer journal 1983, Vol.19 (6), p.525-528
Main Authors: Simionescu, Cr.I., Vasiliu Oprea, Cl, Nicoleanu, J.
Format: Article
Language:English
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Summary:Mechanochemical polymerization by vibratory milling of acrylamide and methacrylamide is discussed. The influences of duration, nature of medium and temperature are examined. The polymers are characterized by elemental analysis, i.r.-spectroscopy. X-ray and by determination of some properties. An anion-radical mechanism is proposed.
ISSN:0014-3057
1873-1945
DOI:10.1016/0014-3057(83)90204-5