Some features of dimethyl diallyl ammonium chloride high conversion polymerization in aqueous solutions

The kinetic features of the high conversion radical polymerization of N, N-dimethyl- N, N-diallyl ammonium chloride (DMDAAC) in aqueous solutions have been studied for the first time. Kinetic measurements have been carried out by calorimetry. Special rheokinetic studies of the DMDAAC polymerization...

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Bibliographic Details
Published in:European polymer journal 1989, Vol.25 (11), p.1095-1098
Main Authors: Topchiev, D.A., Malkanduev, Yu.A., Yanovsky, Yu.G., Oppengeim, V.D., Kabanov, V.A.
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Summary:The kinetic features of the high conversion radical polymerization of N, N-dimethyl- N, N-diallyl ammonium chloride (DMDAAC) in aqueous solutions have been studied for the first time. Kinetic measurements have been carried out by calorimetry. Special rheokinetic studies of the DMDAAC polymerization under conditions of small amplitude cyclic non-destructive deformation (dynamic measurements) produce independent information on the high conversion reaction.
ISSN:0014-3057
1873-1945
DOI:10.1016/0014-3057(89)90163-8