Excess volumes of n-butylamine + an aliphatic ketone at 303.15 K

Excess volumes of methyl ethyl ketone +, methyl n-propyl ketone +, and diethyl ketone + n-butylamine were measured at 303.15 K. These mixtures have negative values of V E with minima occurring from 0.4 to 0.6 mole fraction of n-butylamine. The results suggest that hydrogen-bond interaction between u...

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Bibliographic Details
Published in:The Journal of chemical thermodynamics 1978-01, Vol.10 (8), p.731-733
Main Authors: Sreenivasulu, M, Naidu, P.R
Format: Article
Language:English
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Summary:Excess volumes of methyl ethyl ketone +, methyl n-propyl ketone +, and diethyl ketone + n-butylamine were measured at 303.15 K. These mixtures have negative values of V E with minima occurring from 0.4 to 0.6 mole fraction of n-butylamine. The results suggest that hydrogen-bond interaction between unlike molecules dominates in the mixtures.
ISSN:0021-9614
1096-3626
DOI:10.1016/0021-9614(78)90131-3