Vapour pressures of ( n-hexane + an α,ω-dichloroalkane)

Measurements of vapour-liquid equilibrium pressures by a static method on ( n-hexane + an α,ω-dichloroalkane) at 298.15 K are reported. Activity coefficients and excess molar Gibbs energies were calculated, the latter being strongly positive and generally symmetrical with respect to mole fraction. T...

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Bibliographic Details
Published in:The Journal of chemical thermodynamics 1985-01, Vol.17 (9), p.843-847
Main Authors: Royo, F.M, Gutiérrez Losa, C
Format: Article
Language:English
Subjects:
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
General. Theory
Metals and alloys
Mixtures
Thermodynamic properties
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Summary:Measurements of vapour-liquid equilibrium pressures by a static method on ( n-hexane + an α,ω-dichloroalkane) at 298.15 K are reported. Activity coefficients and excess molar Gibbs energies were calculated, the latter being strongly positive and generally symmetrical with respect to mole fraction. The calculated values of excess molar entropy at x = 0.5 are also given.
ISSN:0021-9614
1096-3626
DOI:10.1016/0021-9614(85)90077-1