High-temperature isopiestic studies on {(1 − y)Hg + y(1 − t)Bi + ytSn}( I) at 600 K. Comparison with the partial ideal-solution model

The activities of Hg in {(1 − y)Hg + y(1 − t)Bi + ytSn} have been measured at 600 K using a high-temperature isopiestic technique. Each entire isopiestic curve of mercury was determined by only one experiment. The activities of Bi and Sn were calculated using an analytical procedure from the ternary...

Full description

Saved in:
Bibliographic Details
Published in:The Journal of chemical thermodynamics 1989-06, Vol.21 (6), p.653-665
Main Authors: Wang, Z.-C., Zhang, X.-H., He, T.-Z., Bao, Y.-H.
Format: Article
Language:English
Subjects:
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The activities of Hg in {(1 − y)Hg + y(1 − t)Bi + ytSn} have been measured at 600 K using a high-temperature isopiestic technique. Each entire isopiestic curve of mercury was determined by only one experiment. The activities of Bi and Sn were calculated using an analytical procedure from the ternary isoactivity results and the selected thermodynamic values for the binary sub-systems {(1 − y)Hg + yBi}, {(1 − y)Hg + ySn}, and {(1 − t)Bi + tSn}. The results approximately fit the partial ideal-solution model proposed previously.
ISSN:0021-9614
1096-3626
DOI:10.1016/0021-9614(89)90178-X