Compressions of some nitriles under pressures up to 150 MPa at 298.15 K

Compressions k of propionitrile (PN), n-butyronitrile ( n-BN), isobutyronitrile ( i-BN), benzonitrile (BzN), and α-tolunitrile (α-TN) were measured at pressures up to 150 MPa at 298.15 K. The measured compressions were fitted to the Tait equation. Isothermal compressibilities κ T for nitriles at 0.1...

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Bibliographic Details
Published in:The Journal of chemical thermodynamics 1990, Vol.22 (8), p.797-801
Main Authors: Uosaki, Yasuhiro, Matsumura, Hajime, Ogiyama, Hideki, Moriyoshi, Takashi
Format: Article
Language:English
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Summary:Compressions k of propionitrile (PN), n-butyronitrile ( n-BN), isobutyronitrile ( i-BN), benzonitrile (BzN), and α-tolunitrile (α-TN) were measured at pressures up to 150 MPa at 298.15 K. The measured compressions were fitted to the Tait equation. Isothermal compressibilities κ T for nitriles at 0.1 MPa were determined from the Tait paramters. The κ T value at 0.1 MPa for nitriles decreases in the sequence: i-BN > PN > n-BN > BzN > α-TN.
ISSN:0021-9614
1096-3626
DOI:10.1016/0021-9614(90)90071-W