Excess molar volumes of mixtures containing 1,2-dichloropropane or 1,3-dichloropropane

Excess molar volumes V m E of [(1− x)( n-C 6 H 14 or n-C 16H 34 or CH 3C(CH 3) 2CH 2CH 3 or c-C 6 H 12 or CCl 4 or C 6 H 6) + x(CH 2 ClCHClCH 3 or CH 2 ClCH 2 CH 2Cl)] at 298.15 and 318.15 K were measured. Mixtures containing 1,2-dichloropropane show V m E values noticeably greater than those of mix...

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Bibliographic Details
Published in:The Journal of chemical thermodynamics 1990-05, Vol.22 (5), p.431-437
Main Authors: Baños, I, Valero, J, Pérez, P, Gracia, M, Gutiérrez Losa, C
Format: Article
Language:English
Subjects:
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
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Summary:Excess molar volumes V m E of [(1− x)( n-C 6 H 14 or n-C 16H 34 or CH 3C(CH 3) 2CH 2CH 3 or c-C 6 H 12 or CCl 4 or C 6 H 6) + x(CH 2 ClCHClCH 3 or CH 2 ClCH 2 CH 2Cl)] at 298.15 and 318.15 K were measured. Mixtures containing 1,2-dichloropropane show V m E values noticeably greater than those of mixtures with 1,3-dichloropropane, and they approach the theoretical Flory's predictions.
ISSN:0021-9614
1096-3626
DOI:10.1016/0021-9614(90)90133-B