Influence of CTAB/1-butanol micelles on crystal violet basic hydrolysis

The influence of CTAB/1-BuOH micelles (hexadecyltrimethylammonium bromide1-butanol) on Crystal Violet basic hydrolysis has been studied. The kinetic results can be explained by means of the pseudophase kinetic model. The results strongly suggest that incorporation of 1-butanol to cationic CTAB micel...

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Bibliographic Details
Published in:Journal of colloid and interface science 1989, Vol.127 (2), p.522-531
Main Authors: Valiente, Mercedes, Rodenas, Elvira
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
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Summary:The influence of CTAB/1-BuOH micelles (hexadecyltrimethylammonium bromide1-butanol) on Crystal Violet basic hydrolysis has been studied. The kinetic results can be explained by means of the pseudophase kinetic model. The results strongly suggest that incorporation of 1-butanol to cationic CTAB micelles displaces the substrate from the micellar into the aqueous phase. Different theoretical approaches are discussed in order to explain the results.
ISSN:0021-9797
1095-7103
DOI:10.1016/0021-9797(89)90056-8