The use of phosphate to generate H-atoms at pH 5–8 as determined by photocurrents: electrochemical properties of H-atoms

The electro-chemical properties of H-atoms at pH 5–8 have been studied based upon photocurrents following the interaction of hydrated electrons with phosphate in aqueous solution. The rate constants for the interaction of e aq − with H 2PO 4 − and HPO 4 2− were determined to be 1.9 × 10 7 dm 3 mol −...

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Bibliographic Details
Published in:Journal of electroanalytical chemistry and interfacial electrochemistry 1990-05, Vol.284 (1), p.59-65
Main Authors: O'NeiIl, P., Busi, F., Concialini, V., Tubertini, O.
Format: Article
Language:English
Subjects:
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
High temperature electrochemistry (including molten salts)
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Summary:The electro-chemical properties of H-atoms at pH 5–8 have been studied based upon photocurrents following the interaction of hydrated electrons with phosphate in aqueous solution. The rate constants for the interaction of e aq − with H 2PO 4 − and HPO 4 2− were determined to be 1.9 × 10 7 dm 3 mol −1 s −1 and
ISSN:0022-0728
DOI:10.1016/0022-0728(90)87062-O