Modelling electrode reactions using the strongly implicit procedure

The strongly implicit procedure is shown to be an easy-to-use stable, rapid and computationally efficient method of solving the coupled mass transport equations which describe complex electrode reactions involving diffusion, convection and homogeneous chemical steps. The method is illustrated with a...

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Bibliographic Details
Published in:Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 1995-02, Vol.383 (1), p.13-19
Main Authors: Compton, Richard G., Dryfe, Robert A.W., Wellington, R.Geoffrey, Hirst, Judy
Format: Article
Language:English
Subjects:
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Mathematical models
Study of interfaces
Transport phenomena
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Summary:The strongly implicit procedure is shown to be an easy-to-use stable, rapid and computationally efficient method of solving the coupled mass transport equations which describe complex electrode reactions involving diffusion, convection and homogeneous chemical steps. The method is illustrated with a diversity of problems pertaining to both microelectrodes and electrodes of conventional dimensions located in a rectangular channel through which electrolyte is pumped under laminar conditions. In all cases excellent agreement with experiment and/or existing analytical or numerical theory is noted.
ISSN:1572-6657
1873-2569
DOI:10.1016/0022-0728(94)03698-3