New pentafluorothio (SF 5)-containing alkyl dibromides

Preparation of two new SF 5-containing compounds and one telomer was achieved by reaction of the olefins CH 2=CHBr and CF 2=CFBr with SF 5Br to form SF 5CH 2CHBr 2 and SF 5CF 2CFBr 2. In the reaction of SF 5Br with CF 2=CFBr, a waxy solid formed with an average formula of SF 5(CF 2CFBr) 10Br.

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Bibliographic Details
Published in:Journal of fluorine chemistry 1996, Vol.76 (1), p.63-65
Main Authors: Terjeson, Robin J., Willenbring, Robert, Gard, Gary L.
Format: Article
Language:English
Subjects:
Alkyl dibromides
IR spectroscopy
Mass spectrometry
NMR spectroscopy
Pentafluorothio group
Preparation
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Summary:Preparation of two new SF 5-containing compounds and one telomer was achieved by reaction of the olefins CH 2=CHBr and CF 2=CFBr with SF 5Br to form SF 5CH 2CHBr 2 and SF 5CF 2CFBr 2. In the reaction of SF 5Br with CF 2=CFBr, a waxy solid formed with an average formula of SF 5(CF 2CFBr) 10Br.
ISSN:0022-1139
1873-3328
DOI:10.1016/0022-1139(95)03341-6