Facile syntheses of tris(trifluoromethyl)phosphine and difluorotris (trifluoromethyl) phosphorane

Tris(trifluoromethyl) phosphine is easily available in high yield using the three component system D(NAt) 2) 3/NF 3Ar/(DhI) 3D in IIDA. Addition of chlorine and fluorination with zinc difluoride yield difluorotris (trifluoromethyl) phosphorane.

Saved in:
Bibliographic Details
Published in:Journal of fluorine chemistry 1996-07, Vol.79 (1), p.103-104
Main Authors: Görg, Michaela, Röschenthaler, Gerd-Volker, Kolomeitsev, Alexander A.
Format: Article
Language:English
Subjects:
Bromotrifluoromethane
Difluorotris (trifluoromethyl) -phosphorane
Hexaethylphosphorus triamide
Triphenylphosphite
Tris(trifluoromethyl)phosphine
Zinc difluoride
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Tris(trifluoromethyl) phosphine is easily available in high yield using the three component system D(NAt) 2) 3/NF 3Ar/(DhI) 3D in IIDA. Addition of chlorine and fluorination with zinc difluoride yield difluorotris (trifluoromethyl) phosphorane.
ISSN:0022-1139
1873-3328
DOI:10.1016/0022-1139(96)03471-9