Experimental determination of the apparent rate constant in the case of the reaction of formation of excimer of 1,2-benzanthracene in viscous solvents

A non-a-priori method is presented in order to compute from the experiment the apparent rate constant of a diffusion-influenced kinetics reaction with excimer formation in viscous solvents. The case of 1,2-benzanthracene is displayed and an unusual behaviour of the apparent rate constant is obtained...

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Bibliographic Details
Published in:Journal of luminescence 1992-12, Vol.54 (4), p.203-207
Main Authors: Duhamel, J., Bouchy, M., Baros, F., Andre, J.C.
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
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Summary:A non-a-priori method is presented in order to compute from the experiment the apparent rate constant of a diffusion-influenced kinetics reaction with excimer formation in viscous solvents. The case of 1,2-benzanthracene is displayed and an unusual behaviour of the apparent rate constant is obtained, in accordance with a previously described model.
ISSN:0022-2313
1872-7883
DOI:10.1016/0022-2313(92)90067-J