Analysis of EPR powder pattern lineshapes for Mn(II) including third-order perturbation corrections. Applications to Mn(II) complexes with enzymes

Third-order perturbation theory is used to obtain expressions for the energy levels of 55Mn(II)( I = 5 2 ; S = 5 2 ) in the presence of an external magnetic field with axial and rhombic distortions in the crystal field. The expressions are used to stimulate line shapes for the central ( 1 2 ↔− 1 2 )...

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Bibliographic Details
Published in:Journal of magnetic resonance (1969) 1979, Vol.33 (3), p.595-602
Main Authors: Markham, George D, Nageswara Rao, B.D, Reed, George H
Format: Article
Language:English
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Summary:Third-order perturbation theory is used to obtain expressions for the energy levels of 55Mn(II)( I = 5 2 ; S = 5 2 ) in the presence of an external magnetic field with axial and rhombic distortions in the crystal field. The expressions are used to stimulate line shapes for the central ( 1 2 ↔− 1 2 ) fine structure transition in the EPR spectra for Mn(II) in complexes with enzymes.
ISSN:0022-2364
1557-8968
DOI:10.1016/0022-2364(79)90171-9