Raman spectra, normal coordinate treatment, and calculated thermodynamic properties for hydrazine and tetradeuterohydrazine

Raman displacements, relative intensities, and depolarization factors have been obtained for liquid hydrazine at room temperature. All available data concerning the structure, Raman and infrared spectra, frequency assignments, and dipole moment measurements were collected and examined for the most r...

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Bibliographic Details
Published in:Journal of molecular spectroscopy 1963, Vol.11 (1), p.163-184
Main Authors: Ziomek, Joseph S., Zeidler, M.D.
Format: Article
Language:English
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Summary:Raman displacements, relative intensities, and depolarization factors have been obtained for liquid hydrazine at room temperature. All available data concerning the structure, Raman and infrared spectra, frequency assignments, and dipole moment measurements were collected and examined for the most reliable values. Results of normal coordinate treatment based on the C 2 model are given and frequency assignments are reviewed. Also, calculated thermodynamic properties for 273.16°K to 1000°K on the basis of the rigid rotator harmonic oscillator approximation are listed. The C 8 model (suggested by others) also was considered.
ISSN:0022-2852
1096-083X
DOI:10.1016/0022-2852(63)90015-8