Analysis of 2 ν1 of HDTe

We have analyzed the 2 ν 1 band of HDTe near 4064 cm −1 for the six stable Te isotopes of mass 130, 128, 126, 125, 124, and 122, fitting them all simultaneously, thereby obtaining values for the ground state molecular constants and upper state constants through fourth power in the angular momenta, i...

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Bibliographic Details
Published in:Journal of molecular spectroscopy 1974, Vol.52 (2), p.196-208
Main Authors: Willson, P.D., Moncur, N.K., Edwards, T.H.
Format: Article
Language:English
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Summary:We have analyzed the 2 ν 1 band of HDTe near 4064 cm −1 for the six stable Te isotopes of mass 130, 128, 126, 125, 124, and 122, fitting them all simultaneously, thereby obtaining values for the ground state molecular constants and upper state constants through fourth power in the angular momenta, including isotopic mass dependencies for A, B, C, and ν 0. More than 700 transitions were assigned and fit with a standard deviation of less than 0.005 cm −1, both for the Watson reduced Hamiltonian and for a Kivelson-Wilson Hamiltonian reduced by the planarity relationships.
ISSN:0022-2852
1096-083X
DOI:10.1016/0022-2852(74)90110-6