The ν11 band of cyanuric fluoride

The rotationally resolved spectrum of the ν 11 band of cyanuric fluoride (out-of-plane ring bending), which is centered near 820 cm −1, was obtained using a Bruker IFS 120 HR Fourier Transform spectrometer. The parallel band shows well defined P, Q, and R branches and only a very slight degradation...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular spectroscopy 1992, Vol.152 (2), p.317-327
Main Authors: Fleming, Patrick E., Mathews, C.Weldon
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The rotationally resolved spectrum of the ν 11 band of cyanuric fluoride (out-of-plane ring bending), which is centered near 820 cm −1, was obtained using a Bruker IFS 120 HR Fourier Transform spectrometer. The parallel band shows well defined P, Q, and R branches and only a very slight degradation to longer wavelengths. Data at a resolution of 0.01 cm −1 led to ground vibrational state rotational constants of B 0 = 0.065 608 4 (36) cm −1 and D J = 3.88(34) × 10 −9cm −1 based on 170 assigned lines. The K structure is not resolved. “Satellites” to the rotational structure of the ν 11 band are assigned to hot bands associated with low-lying vibrational levels which are significantly populated at room temperature.
ISSN:0022-2852
1096-083X
DOI:10.1016/0022-2852(92)90072-V