Relationship between OH stretching frequencies of phenol-π- OR n-bases complexes and the chemical shifts of phenolic carbons

The aromatic carbon shifts induced by hydrogen bonding have been measured for complexes between phenol and π or n bases (from benzene to collidine) of largely variable strength. The ipso chemical shift corrected for anisotropic and non-specific medium effects correlates linearly with the shift of th...

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Bibliographic Details
Published in:Journal of molecular structure 1985, Vol.127 (3), p.297-303
Main Authors: Moreau-Descoings, Marie-Christine, Guillaume-Vilport, Frédérique, Seguin, Jean-Paul, Uzan, Raoul, Doucet, Jean-Pierre
Format: Article
Language:English
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Summary:The aromatic carbon shifts induced by hydrogen bonding have been measured for complexes between phenol and π or n bases (from benzene to collidine) of largely variable strength. The ipso chemical shift corrected for anisotropic and non-specific medium effects correlates linearly with the shift of the OH vibration of the bonded phenol.
ISSN:0022-2860
1872-8014
DOI:10.1016/0022-2860(85)80012-0