The molecular structure and conformational behaviour of 3-methyl-3-phenyl-cyclopropene

The molecular structure and conformational properties of 3-methyl-3-phenyl-cyclopropene have been studied by the gas electron diffraction method. The experimental data are in accordance with a bisected conformer having a C 3C Ar twist angle of 38° or with a conformational mixture constisting of 64%...

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Bibliographic Details
Published in:Journal of molecular structure 1985-01, Vol.128 (1), p.207-216
Main Authors: Traetteberg, M., De Meijere, A., Domnin, I.N.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Exact sciences and technology
Interatomic distances and angles
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
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Summary:The molecular structure and conformational properties of 3-methyl-3-phenyl-cyclopropene have been studied by the gas electron diffraction method. The experimental data are in accordance with a bisected conformer having a C 3C Ar twist angle of 38° or with a conformational mixture constisting of 64% of the bisected conformer (θ(C 3C Ar) = 0°) and 36% of the perpendicular conformer (θ(C 3C Ar) = 90°).
ISSN:0022-2860
1872-8014
DOI:10.1016/0022-2860(85)85052-3