Normal coordinate analysis of cyclopropane adsorbed on faujasite and mordenite surfaces

A normal coordinate analysis was carried out for cyclopropane in the free and the adsorbed state applying a valence force field. The lacking influence of the zeolite module confirms a location near to the cations. The changes of the force constants can be explained by alternations of the geometric a...

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Bibliographic Details
Published in:Journal of molecular structure 1986-03, Vol.143, p.271-274
Main Authors: Förster, H., Seebode, J., Zakharieva-Pencheva, O.
Format: Article
Language:English
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Summary:A normal coordinate analysis was carried out for cyclopropane in the free and the adsorbed state applying a valence force field. The lacking influence of the zeolite module confirms a location near to the cations. The changes of the force constants can be explained by alternations of the geometric as well as the electronic structure of cyclopropane and the hindrance of the bending vibration due to the interaction with the zeolite surface.
ISSN:0022-2860
1872-8014
DOI:10.1016/0022-2860(86)85255-3