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Influences of surface reflections on diffuse reflectance measurements

When the diffuse reflectance of a compact, i.e. non-particulate solid sample is measured, regular reflection at the surface cannot be avoided: external reflection occurs when the sample is irradiated, and internal reflection occurs when radiation emerges from the sample. Both processes can cause sev...

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Bibliographic Details
Published in:Journal of molecular structure 1990-03, Vol.218, p.381-386
Main Authors: Korte, E.H., Staat, H.
Format: Article
Language:English
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Summary:When the diffuse reflectance of a compact, i.e. non-particulate solid sample is measured, regular reflection at the surface cannot be avoided: external reflection occurs when the sample is irradiated, and internal reflection occurs when radiation emerges from the sample. Both processes can cause severe spectral distortions of the diffuse-reflectance spectrum which seem to be particularly troublesome in the infrared range. These are discussed here along with results from calculations for the internal reflectance.
ISSN:0022-2860
1872-8014
DOI:10.1016/0022-2860(90)80297-W