Synthesis and x-ray structural investigation of 1-(4-Methoxyphenyl)-3-phenoxy-4-methylthio-4- methoxyimino-2-azetidinones

The trans- ( 3) and cis- ( 4) isomers of 1- (4-methoxyphenyl)-3-phenoxy-4-methylthio-4- methoxyimino-2-azetidinone have been synthesized. The structure of 3 has been investigated by X-ray diffraction. The compound crystallizes in a monoclinic system, space group P2 1/ a, Z= 4, a=7.377(2), b=23.790(3...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular structure 1991-04, Vol.244, p.249-257
Main Authors: Gluziński, P., Grochowski, E., Krajewski, J.W., Pupek, K.
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Heterocyclic compounds
Organic compounds
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The trans- ( 3) and cis- ( 4) isomers of 1- (4-methoxyphenyl)-3-phenoxy-4-methylthio-4- methoxyimino-2-azetidinone have been synthesized. The structure of 3 has been investigated by X-ray diffraction. The compound crystallizes in a monoclinic system, space group P2 1/ a, Z= 4, a=7.377(2), b=23.790(3), c=10.724(2) Å, β=95.01(2)°. The structure was solved by direct methods and refined by a full-matrix, least-squares procedure to R = 0.0435, R w = 0.0597, w = 1.92/ (σ 2 F + 0.002 F 2). The solid-state structure was compared with the structure found from NMR studies in solution.
ISSN:0022-2860
1872-8014
DOI:10.1016/0022-2860(91)80160-6