Multiple-pulse NQR dynamics of spin systems with strong heteronuclear coupling

The results are presented of a theoretical consideration of the nuclear quadrupole resonance (NQR) and spin—spin relaxation for a paramagnetic body containing nuclei of two different sorts coupled by the strong homonuclear and heteronuclear dipole—dipole interactions and influenced by an external mu...

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Bibliographic Details
Published in:Journal of molecular structure 1994-05, Vol.321 (3), p.239-244
Main Authors: Furman, G.B., Shaposhnikov, I.G.
Format: Article
Language:English
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Summary:The results are presented of a theoretical consideration of the nuclear quadrupole resonance (NQR) and spin—spin relaxation for a paramagnetic body containing nuclei of two different sorts coupled by the strong homonuclear and heteronuclear dipole—dipole interactions and influenced by an external multiple-pulse radiofrequency magnetic field acting only on nuclei of one sort. Kinetic equations were obtained giving the possibility of finding the time dependence of the magnetization of the body and the kinetic coefficients calculated as a function of the multiple-pulse field parameters. The possibilities of using the results in question for molecular structure and molecular dynamics investigations are briefly surveyed.
ISSN:0022-2860
1872-8014
DOI:10.1016/0022-2860(93)07950-2