Study of the contribution from the J = 1 and J = 2 parts of the anisotropic potential to the far-infrared spectra of HCl in Ar, Kr and Xe liquids

The present work applies a non-Markovian spectral theory to investigate the influence of the J = 1 and J = 2 anisotropic terms of the solute-solvent intermolecular potential to the far infrared (FIR) spectrum or HCl in Ar and T = 105 K, Kr ( T = 125 K), Xe ( T = 175 K) liquids. The obtained results...

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Bibliographic Details
Published in:Journal of molecular structure 1993-03, Vol.294, p.99-102
Main Authors: Roco, J.M.M., Medina, A., Velasco, S.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Effects of atomic and molecular interactions on electronic structure
Electronic structure of atoms, molecules and their ions: theory
Environmental and solvent effects
Exact sciences and technology
Physics
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Summary:The present work applies a non-Markovian spectral theory to investigate the influence of the J = 1 and J = 2 anisotropic terms of the solute-solvent intermolecular potential to the far infrared (FIR) spectrum or HCl in Ar and T = 105 K, Kr ( T = 125 K), Xe ( T = 175 K) liquids. The obtained results show that, in all cases, the main contribution to the respective FIR spectrum comes from the J = 1 part, while the J = 2 part leads to a smoothing of the rotational structure and a slight increasing of the absorption in the high frequency range.
ISSN:0022-2860
1872-8014
DOI:10.1016/0022-2860(93)80324-O