An infrared and Raman study of new lonic-conductor lithium glasses

New vitreous fast ionic conductors in the system B 2O 3Li 2OLiCl are described. The conductivity of these glasses increases with the Li 2O and particularly with the LiCl contents. A Raman and infrared study undertaken to elucidate the “structure” of the glasses and the conduction mechanism indicat...

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Bibliographic Details
Published in:Journal of solid state chemistry 1980-03, Vol.31 (3), p.285-294
Main Authors: Irion, M., Couzi, M., Levasseur, A., Reau, J.M., Brethous, J.C.
Format: Article
Language:English
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Summary:New vitreous fast ionic conductors in the system B 2O 3Li 2OLiCl are described. The conductivity of these glasses increases with the Li 2O and particularly with the LiCl contents. A Raman and infrared study undertaken to elucidate the “structure” of the glasses and the conduction mechanism indicates that the structure consists of a “covalent” boron-oxygen network, in which LiCl is “diluted” without producing detectable interactions with the latter.
ISSN:0022-4596
1095-726X
DOI:10.1016/0022-4596(80)90090-0