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α- and β-ruthenium trichloride

Published information on ruthenium trichloride is discrepant and confusing. Although two forms of the compound have been recognised, the means of preparing each in a pure form and of rigorously establishing its purity have been lacking. A detailed physico-chemical examination of the materials produc...

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Bibliographic Details
Published in:Journal of the less-common metals 1965-01, Vol.8 (6), p.428-434
Main Authors: Hyde, K.R, Hooper, E.W, Waters, J, Fletcher, J.M
Format: Article
Language:English
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Summary:Published information on ruthenium trichloride is discrepant and confusing. Although two forms of the compound have been recognised, the means of preparing each in a pure form and of rigorously establishing its purity have been lacking. A detailed physico-chemical examination of the materials produced during a systematic re-investigation of the chlorination of ruthenium metal has led to the development of methods for the preparation of pure α- and β-RuCl 3. The properties of the two forms and their relation to each other are described.
ISSN:0022-5088
DOI:10.1016/0022-5088(65)90082-2