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Limonoids from Turraea floribunda

Extracts of the root bark of Turraea floribunda have yielded four new limonoids of the havanensin class: 28-nor-4α-carbomethoxy-11β-acetoxy-12α-(2-methylbutanoyloxy)-14,15-deoxyhavanensin-1,7-diacetate; 28-nor-4α-carbomethoxy-11β-hydroxy-12α-(2-methylbutanoyloxy)-14,15-deoxyhavanensin-1,7-diacetate;...

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Bibliographic Details
Published in:Phytochemistry (Oxford) 1995-09, Vol.40 (1), p.239-243
Main Authors: Torto, Baldwyn, Bentley, Michael D., Cole, Barbara J.W., Hassanali, Ahmed, Huang, Fu-Yung, Gelbaum, Leslie, Vanderveer, Donald G.
Format: Article
Language:English
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Summary:Extracts of the root bark of Turraea floribunda have yielded four new limonoids of the havanensin class: 28-nor-4α-carbomethoxy-11β-acetoxy-12α-(2-methylbutanoyloxy)-14,15-deoxyhavanensin-1,7-diacetate; 28-nor-4α-carbomethoxy-11β-hydroxy-12α-(2-methylbutanoyloxy)-14,15-deoxyhavanensin-1,7-diacetate; 18-nor-4α-carbomethoxy-11β-acetoxy-12α-(2-methylbutanoyloxy)-14,15-deoxyhavanensin-1-acetate; and 28-nor-4α-carbomethoxy-7-deoxy-7-oxo-11β-acetoxy-12α-(2-methylbutanoyloxy)-14,15-deoxyhavanensin-1-acetate. The structures were determined by spectroscopic methods. The structure for the first of these compounds was also confirmed by X-ray diffraction methods.
ISSN:0031-9422
1873-3700
DOI:10.1016/0031-9422(95)00198-G