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Viscometric study of the polyisobutylene-chlorobenzene system

The theta temperature and the interaction parameters have been determined for the polyisobutylene-chlorobenzene system by the viscometric method developed by Fox and Flory (F-F). Improved calorimetric data on the same system (and on the polyisobutylene-benzene and polyisobutylene-toluene systems) gi...

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Bibliographic Details
Published in:Polymer (Guilford) 1961, Vol.2, p.393-399
Main Authors: Daoust, H., Senez, M.
Format: Article
Language:English
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Summary:The theta temperature and the interaction parameters have been determined for the polyisobutylene-chlorobenzene system by the viscometric method developed by Fox and Flory (F-F). Improved calorimetric data on the same system (and on the polyisobutylene-benzene and polyisobutylene-toluene systems) give heat parameters which are higher than those calculated according to the F-F treatment. On the other hand, the Kurata-Yamakawa treatment of viscometric data gives interaction parameters which are in better agreement with those determined calorimetrically. A comparison between the two treatments is discussed in this paper.
ISSN:0032-3861
1873-2291
DOI:10.1016/0032-3861(61)90044-1