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Viscometric study of the polyisobutylene-chlorobenzene system
The theta temperature and the interaction parameters have been determined for the polyisobutylene-chlorobenzene system by the viscometric method developed by Fox and Flory (F-F). Improved calorimetric data on the same system (and on the polyisobutylene-benzene and polyisobutylene-toluene systems) gi...
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Published in: | Polymer (Guilford) 1961, Vol.2, p.393-399 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The theta temperature and the interaction parameters have been determined for the polyisobutylene-chlorobenzene system by the viscometric method developed by Fox and Flory (F-F). Improved calorimetric data on the same system (and on the polyisobutylene-benzene and polyisobutylene-toluene systems) give heat parameters which are higher than those calculated according to the F-F treatment. On the other hand, the Kurata-Yamakawa treatment of viscometric data gives interaction parameters which are in better agreement with those determined calorimetrically. A comparison between the two treatments is discussed in this paper. |
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ISSN: | 0032-3861 1873-2291 |
DOI: | 10.1016/0032-3861(61)90044-1 |