Studies on the reactivity of polymers 2: Chlorination of poly(vinylidene chloride) by sulphuryl chloride in the presence of azobisisobutyronitrile

Studies of poly(vinylidene chloride) by sulphuryl chloride in the presence of a radical-creating initiator asobisisobutyronitrile are presented. The chlorination rate is defined for a methylene group occurring in the -CCl 2-CH 2CCl 2-sequence.

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Bibliographic Details
Published in:Polymer (Guilford) 1984, Vol.25 (9), p.1371-1373
Main Authors: Sikorski, Ryszard T, Czerwińska, Elzbieta
Format: Article
Language:English
Subjects:
Chlorination
kinetics
micro-structure
poly(vinylidene chloride)
sulphuryl chloride
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Description
Summary:Studies of poly(vinylidene chloride) by sulphuryl chloride in the presence of a radical-creating initiator asobisisobutyronitrile are presented. The chlorination rate is defined for a methylene group occurring in the -CCl 2-CH 2CCl 2-sequence.
ISSN:0032-3861
1873-2291
DOI:10.1016/0032-3861(84)90394-X