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Effect of alkyl substituents on the reactivity of alkyl iodides in telomerization with ethylene

In [1], on the example of the telomerization of ethylene with ethyl iodide, we developed a method for determining chain transfer constants taking account of the gradual reaction of the telomers and reversibility of the chain transfer reaction. In the present investigation this procedure was used to...

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Bibliographic Details
Published in:Polymer science USSR 1966, Vol.8 (2), p.307-312
Main Authors: Katsobashvili, V.Ya, Safronenko, Ye.D., Afanas'yev, I.B.
Format: Article
Language:English
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Summary:In [1], on the example of the telomerization of ethylene with ethyl iodide, we developed a method for determining chain transfer constants taking account of the gradual reaction of the telomers and reversibility of the chain transfer reaction. In the present investigation this procedure was used to study the influence of the telogen structure, and of temperature, in telomerization with ethylene on the chain transfer constants.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(66)90393-5