Reaction of p-nitrosodiphenylamine with isoprene rubber

A study was made of the reaction of p-nitrosodiphenylamine (PNDPA) with isoprene rubber and it was established that it takes place through nitroso-groups and results in the formation of at least two N-phenyl- p-phenylenediamine derivatives, of which one is added to the macro-molecule, while the othe...

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Bibliographic Details
Published in:Polymer science USSR 1973, Vol.15 (10), p.2695-2699
Main Authors: Kavun, S.M, Fedorova, T.V, Akin'shina, G.I, Tarasova, Z.N, Khodzhayeva, I.V
Format: Article
Language:English
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Summary:A study was made of the reaction of p-nitrosodiphenylamine (PNDPA) with isoprene rubber and it was established that it takes place through nitroso-groups and results in the formation of at least two N-phenyl- p-phenylenediamine derivatives, of which one is added to the macro-molecule, while the other has a low molecular weight. A mechanism is proposed for the reaction of PNDPA with isoprene rubber.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(73)90034-8