Some peculiarities of applying the free volume theory to the dielectrical parameters of polymers

This work compares the free volume theory and of the known hybrid equation for the relaxations of the kinetic elements of polar polymers with the experimental dielectrical parameters of polychloroprene (PCP). The energy factor of the hybrid equation applied to PCP has been established as a function...

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Bibliographic Details
Published in:Polymer science USSR 1977, Vol.19 (10), p.2613-2618
Main Authors: Yegurtdzhyan, Sh.T, Petrosyan, V.P
Format: Article
Language:English
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Summary:This work compares the free volume theory and of the known hybrid equation for the relaxations of the kinetic elements of polar polymers with the experimental dielectrical parameters of polychloroprene (PCP). The energy factor of the hybrid equation applied to PCP has been established as a function of the free volume for the temperature close to the glass temperature of the sample.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(77)90344-6