Radical polymerization of benzyl methacrylate at high degrees of conversion

A calorimetric study was made of radical polymerization of benzyl methacrylate at 30, 50 and 60°. Intermittent illumination and results of the rate of initiation at various stages of conversion were used to determine kinetic parameters of polymerization at degrees of 3, 15, 40, 50 and 80%. The varia...

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Bibliographic Details
Published in:Polymer science USSR 1978, Vol.20 (4), p.1030-1037
Main Authors: Surovtsev, L.G., Bulatov, M.A., Spasskii, S.S., Charushnikov, K.A.
Format: Article
Language:English
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Summary:A calorimetric study was made of radical polymerization of benzyl methacrylate at 30, 50 and 60°. Intermittent illumination and results of the rate of initiation at various stages of conversion were used to determine kinetic parameters of polymerization at degrees of 3, 15, 40, 50 and 80%. The variation of parameters with the extent of reaction is interpreted from the point of view of elementary stages of polymerization at advanced degrees.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(78)90303-9