The synthesis and heterogeneous structures of the anionic oligo-ester acrylate (OEA) networks

Polymeric networks based on bis-trimethylene glycol-bis-diethylene glyco-, and bis-ethylene glycol-α,ω-dimethacryl phthalates have been synthesized by the anionic mechanism of polymerization. The steric polymer yields have been determined as a function of catalyst concentration. The produced crossli...

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Bibliographic Details
Published in:Polymer science USSR 1978, Vol.20 (9), p.2261-2268
Main Authors: Lipatova, T.E., Kuz'menko, L.S., Shilov, V.V., Minenko, N.N.
Format: Article
Language:English
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Summary:Polymeric networks based on bis-trimethylene glycol-bis-diethylene glyco-, and bis-ethylene glycol-α,ω-dimethacryl phthalates have been synthesized by the anionic mechanism of polymerization. The steric polymer yields have been determined as a function of catalyst concentration. The produced crosslinked polymers were examined by small angle X-ray; the type of the heterogeneous structure and the formation conditions were correlated with the polymerization conditions. The parameters of the micro-heterogeneous network structure have been determined and the link found with the geometrical features of the initial oligomer chains, as well as the synthesis conditions.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(78)90394-5