Investigation of free radical reactions in the modification of polyisoprene with p-nitrosodiphenylamine

The radical mechanism for the reaction between polyisoprene and p-nitrosodiphenylamine, which had been proposed previously, has been confirmed. The kinetics of formation of carbon centred macroradicals and the effect of the anti-oxidant N-isopropyl-N′-phenyl- p-phenylenediamine on this process have...

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Bibliographic Details
Published in:Polymer science USSR 1979, Vol.21 (5), p.1125-1130
Main Authors: Kavun, S.M., Shankin, S.N.
Format: Article
Language:English
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Summary:The radical mechanism for the reaction between polyisoprene and p-nitrosodiphenylamine, which had been proposed previously, has been confirmed. The kinetics of formation of carbon centred macroradicals and the effect of the anti-oxidant N-isopropyl-N′-phenyl- p-phenylenediamine on this process have been investigated.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(79)90009-1