Thermal degradation of polyimides based on 1,7- m- and 1,12- p-carboranylenediamines

The thermal degradation of polyimides based on 1,7- m- and 1,12- p-carboranylened-iamines has been investigated in the temperature range 100–600°C. It has been established that the introduction of m-carborane fragments into the polyimide chain reduces the rate of homolytic and heterolytic decomposit...

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Bibliographic Details
Published in:Polymer science USSR 1979, Vol.21 (2), p.332-338
Main Authors: Korshak, V.V., Pavlova, S.-S.A., Gribkova, P.N., Balykova, T.N., Mikadze, L.A., Bekasova, N.I., Prigozhina, M.P.
Format: Article
Language:English
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Summary:The thermal degradation of polyimides based on 1,7- m- and 1,12- p-carboranylened-iamines has been investigated in the temperature range 100–600°C. It has been established that the introduction of m-carborane fragments into the polyimide chain reduces the rate of homolytic and heterolytic decomposition of the imide link to a greater extent than that which occurs when p-carborane rings are introduced.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(79)90250-8