Synthesis of bioresistant polymers and block copolymers using initiating systems based on mixed metalorganic compounds of mercury, tin and lead

A study has been made of the initiating capacity of binary systems based on mixed metalorganic compounds of mercury, tin and lead and sodium boron hydride or tetraphenylborate in the polymerization of vinyl monomers. It was found that metalorganic radicals are incorporated in the polymer chains as e...

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Bibliographic Details
Published in:Polymer science USSR 1981, Vol.23 (3), p.643-649
Main Authors: Razuvayev, G.A., Zhil'tsov, S.F., Lyadkova, L.I., Kashayeva, V.N., Sokolova, V.A., Mazanova, L.M.
Format: Article
Language:English
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Summary:A study has been made of the initiating capacity of binary systems based on mixed metalorganic compounds of mercury, tin and lead and sodium boron hydride or tetraphenylborate in the polymerization of vinyl monomers. It was found that metalorganic radicals are incorporated in the polymer chains as end units during initiating steps. This leads to the resulting polymers having resistance towards mould fungus. It is shown that the polymers may also be used for the initiation of secondary polymerization and for the synthesis of block copolymers.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(81)90010-1