Role of physical impairment of a polymeric medium during chemicomechanical degradation of triacetylcellulose

The overall impairmet of a loaded polymer specimen when radical reactions are initiated is made up of the primary chemical impairment and subsequent relaxation processes related to structural regrouping of polymer under load (in such cases the stress does not influence the rate of chemical reactions...

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Bibliographic Details
Published in:Polymer science USSR 1981, Vol.23 (2), p.431-439
Main Authors: Mikheyev, Yu.A., Guseva, L.N., Rogova, L.S., Toptygin, D.Ya
Format: Article
Language:English
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Summary:The overall impairmet of a loaded polymer specimen when radical reactions are initiated is made up of the primary chemical impairment and subsequent relaxation processes related to structural regrouping of polymer under load (in such cases the stress does not influence the rate of chemical reactions).
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(81)90185-4