Methods of crosslinking unsaturated carborane-containing polymers and a study of the properties of their copolymers

The influence of the structure of unsaturated organoborane (carborane)-containing polyesters on their reactivity towards copolymerization with vinyl compounds in solution, in the presence of radical and ionic catalysts, in emulsion with radical-type catalysts, in bulk using a thermochemical method a...

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Bibliographic Details
Published in:Polymer science USSR 1983, Vol.25 (5), p.1143-1152
Main Authors: Korshak, V.V., Bekasova, N.I., Solomatina, A.I., Vagina, Zh.P., Klimentova, N.V., Suprun, A.P.
Format: Article
Language:English
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Summary:The influence of the structure of unsaturated organoborane (carborane)-containing polyesters on their reactivity towards copolymerization with vinyl compounds in solution, in the presence of radical and ionic catalysts, in emulsion with radical-type catalysts, in bulk using a thermochemical method and under γ-irradiation at high pressure, has been examined. Certain properties of the resulting copolymers were studied. It was found that copolymers based on the above polyesters are characterized by higher stability towards thermal oxidation and higher adhesional parameters than analogous copolymers without organoborane units.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(83)90014-X