Study of kinetics and the mechanism of graft polymerization of dimethylaminoethyl methacrylate on polycaproamide in the presence of reversible initiating systems

A study was made of kinetic regularities of graft polymerization of dimethylaminoethyl methacrylate on polycaproamide in the presence of an initiating system (phthalocyanine complex of copper-cumene hydroperoxide-ascrobic acid). The process is accompanied by homopolymerization of the monomer. Views...

Full description

Saved in:
Bibliographic Details
Published in:Polymer science USSR 1983, Vol.25 (5), p.1271-1278
Main Authors: Kislyuk, M.S., Gabrielyan, G.A., Gal'braikh, L.S., Rogovin, Z.A.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A study was made of kinetic regularities of graft polymerization of dimethylaminoethyl methacrylate on polycaproamide in the presence of an initiating system (phthalocyanine complex of copper-cumene hydroperoxide-ascrobic acid). The process is accompanied by homopolymerization of the monomer. Views were formulated about the reaction mechanism and causes of differences in kinetic parameters of graft polymerization and homopolymerization are described.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(83)90031-X