Investigation of certain features of the coordination polymerization of α-oxides, exemplified by the formation of U (IV) alkoxyhalides

Nuclear magnetic resonance and conductometry have been used to investigate the interaction between uranium tetrachloride and α-oxides. It has been shown that the oxide ring opens under the influence of UCl 4. The formation of a coordination bond between an oxygen atom of the polyether chain and a ca...

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Bibliographic Details
Published in:Polymer science USSR 1985, Vol.27 (10), p.2362-2367
Main Authors: Khvostik, G.M., Minevich, V.Ya, Shupik, A.N., Sokolov, V.N., Kondratenkov, G.P.
Format: Article
Language:English
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Summary:Nuclear magnetic resonance and conductometry have been used to investigate the interaction between uranium tetrachloride and α-oxides. It has been shown that the oxide ring opens under the influence of UCl 4. The formation of a coordination bond between an oxygen atom of the polyether chain and a catalytic centre has been established, which leads to a slow chain propagation reaction. A general scheme for the interaction between UCl 4 and PO is put forward.
ISSN:0032-3950
1878-268X
DOI:10.1016/0032-3950(85)90315-6