Surface vibrational spectroscopy of molecular adsorbates on metals and semiconductors by infrared-visible sum-frequency generation

We demonstrate the applicability of surface vibrational spectroscopy using infrared-visible sum-frequency generation to molecules adsorbed on metals and semiconductors. The spectra of CH stretches of octadecyltrichlorosilane on silicon and aluminum and ethylidyne on Rh(111) are presented as examples...

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Bibliographic Details
Published in:Surface science 1988, Vol.200 (1), p.L445-L450
Main Authors: Superfine, R., Guyot-Sionnest, P., Hunt, J.H., Kao, C.T., Shen, Y.R.
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Solid-liquid interface
Surface physical chemistry
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Summary:We demonstrate the applicability of surface vibrational spectroscopy using infrared-visible sum-frequency generation to molecules adsorbed on metals and semiconductors. The spectra of CH stretches of octadecyltrichlorosilane on silicon and aluminum and ethylidyne on Rh(111) are presented as examples.
ISSN:0039-6028
1879-2758
DOI:10.1016/0039-6028(88)90422-0