Glycosylation reactions of 6-nitro-1,3-dideazapurine and 6-nitro-1-deazapurine

In glycosylations utilizing SnCl 4 activation or S N2 displacement of the α-chlorosugar, two closely related purines, namely 6-nitro-1,3-dideazapurine 1 and 6-nitro-1-deazapurine 2, give different distributions of isomeric products. In glycosylation utilizing SnCl 4 activation or S N2 displacement o...

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Bibliographic Details
Published in:Tetrahedron letters 1995-03, Vol.36 (10), p.1601-1604
Main Authors: Devlin, Theresa A., Lacrosaz-Rouanet, Emmanuelle, Duc Vo, Jebaratnam, David J.
Format: Article
Language:English
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Summary:In glycosylations utilizing SnCl 4 activation or S N2 displacement of the α-chlorosugar, two closely related purines, namely 6-nitro-1,3-dideazapurine 1 and 6-nitro-1-deazapurine 2, give different distributions of isomeric products. In glycosylation utilizing SnCl 4 activation or S N2 displacement of the α-chlorosugar, two closely related purines, namely 6-nitro-1,3-dideazapurine 1 and 6-nitro-1-deazapurine 2, give different distributions of isomeric products.
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(95)00098-W