Synthesis of 3-aryl-1-butenes by the nickel catalyzed hydrovinylation of styrene derivatives

The synthesis of 3-aryl-1-butenes is performed by hydrovinylation of styrene and alkylsubstituted styrenes catalyzed by [Ni(MeCN) 6][BF 4] 2/Et 2AlCl/PPh 3 under mild conditions with very good activities and selectivities. The synthesis of 3-aryl-1-butenes is performed by hydrovinylation of styrene...

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Bibliographic Details
Published in:Tetrahedron letters 1996-02, Vol.37 (8), p.1157-1160
Main Authors: Monteiro, Adriano Lisboa, Seferin, Marcus, Dupont, Jairton, de Souza, Roberto Fernando
Format: Article
Language:English
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Summary:The synthesis of 3-aryl-1-butenes is performed by hydrovinylation of styrene and alkylsubstituted styrenes catalyzed by [Ni(MeCN) 6][BF 4] 2/Et 2AlCl/PPh 3 under mild conditions with very good activities and selectivities. The synthesis of 3-aryl-1-butenes is performed by hydrovinylation of styrene and alkyl-substituted styrenes catalyzed by [Ni(MeCN) 6][BF 4] 2/Et 2AlCl/PPh 3 under mild conditions with very good activities and selectivities.
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(95)02389-5