Transformation of 1-alkyl-substituted indene ozonides and the corresponding solvent-derived ozonolysis products to tricyclic peroxides: Isolation and characterization of novel hexoxecane derivative

Acidolysis of 1-alkyl-substituted indene ozonides 3a,c,d or the corresponding solvent-derived ozonolysis products 5a-d gave the hexoxecane derivatives 4a-d. The structure of the compound 4a was unambiguously established by the X-ray crystallographic analysis, which demonstrated that the hexoxecane 4...

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Bibliographic Details
Published in:Tetrahedron letters 1996-03, Vol.37 (12), p.2093-2096
Main Authors: Ushigoe, Yoshihiro, Kawamura, Shin-ichi, Teshima, Koichi, Nojima, Masatomo, McCullough, Kevin J.
Format: Article
Language:English
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Summary:Acidolysis of 1-alkyl-substituted indene ozonides 3a,c,d or the corresponding solvent-derived ozonolysis products 5a-d gave the hexoxecane derivatives 4a-d. The structure of the compound 4a was unambiguously established by the X-ray crystallographic analysis, which demonstrated that the hexoxecane 4a is derived from dimerization of molecules of 3a or 5a of the same configuration. Acidolysis of 1-alkyl-substituted indene ozonides 3a,c,d or the corresponding solvent-derived ozonolysis products 5a-d gave the hexoxecane derivatives 4a-d.
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(96)00201-8