Solid miscibility of common-anion lithium and sodium halides. Experimental determination of the region of demixing in lithium bromide + sodium bromide

The region of demixing of solid lithium bromide + sodium bromide mixtures has been measured by X-ray diffraction. The critical temperature of mixing corresponding to a thermodynamic fit of the experimental data is 513 K. Estimates are given of the regions of demixing in solid lithium chloride + sodi...

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Bibliographic Details
Published in:Thermochimica acta 1984-05, Vol.76 (1), p.171-178
Main Authors: Doornhof, D., Van Wijk, H.J., Oonk, H.A.J.
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Liquid-liquid equilibria
Liquid-solid equilibria
Liquid-vapor equilibria
Others (including liquid-liquid-vapor equilibria)
Phase equilibria
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Summary:The region of demixing of solid lithium bromide + sodium bromide mixtures has been measured by X-ray diffraction. The critical temperature of mixing corresponding to a thermodynamic fit of the experimental data is 513 K. Estimates are given of the regions of demixing in solid lithium chloride + sodium chloride and solid lithium iodide + sodium iodide.
ISSN:0040-6031
1872-762X
DOI:10.1016/0040-6031(84)87015-X