Heat capacities of binary mixtures of n-dodecane with hexane isomers

Volumetric heat capacities were measured for binary mixtures of n-dodecane with 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, and 2,3-dimethylbutane at 298.15 K in a Picker flow microcalorimeter. The results were combined with previously published excess molar volumes to obtain excess molar...

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Bibliographic Details
Published in:Thermochimica acta 1986-06, Vol.102, p.75-81
Main Authors: Benson, George C., D'Arcy, Patrick J.
Format: Article
Language:English
Subjects:
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
General. Theory
Metals and alloys
Mixtures
Thermodynamic properties
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Summary:Volumetric heat capacities were measured for binary mixtures of n-dodecane with 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, and 2,3-dimethylbutane at 298.15 K in a Picker flow microcalorimeter. The results were combined with previously published excess molar volumes to obtain excess molar isobaric heat capacities. Use of the Flory theory of mixtures to interpret the results is discussed.
ISSN:0040-6031
1872-762X
DOI:10.1016/0040-6031(86)85315-1